METAN KISLOTA, BUTIN-2-DIOL-1,4 VA BUTIN-2-DIOL-1,4 DIFORMIATLARNING HUMO VA LUMO QIYMATLARINI GAUSSIAN DASTURINING DFT BLYP 6-31G BAZIS TO‘PLAMI YORDAMIDA TAHLIL QILISH
Keywords:
atsetilen, butin-2-diol-1,4, metan kislota, butin-2-diol-1,4 diformiat, organik sintez, eterifikatsiya, guassian dasturiAbstract
Ushbu maqolada Gaussian dasturining DFT BLYP 6-31G bazis to‘plami yordamida metan kislota, butin-2-diol-1,4 hamda shu moddalarning o‘zaro eterifikatsiya reaksiyasi natijasida hosil bo‘lgan butin-2-diol-1,4 diformiatlarning HUMO va LUMO qiymatlari aniqlandi. O‘rganilgan moddalar molekulalarining energetik tahlili qilindi.
References
1. Меркулов В.В., Алмазов А.И., Мантлер С.Н., Жуманазарова Г.М. Синтез непредельного ацетиленового спирта – диметилдигексилбутиндиола // Современные наукоемкие технологии, 2019, № 3-1. – С. 54-59.
2. Schmidt E.Yu., Cherimichkina N.A., Bidusenko I.A., Protsuk N.I., Mikhaleva A.I. and Trofimov B.A. Alkynylation of Aldehydes and Ketones Using the Bu4NOH/H2O/DMSO Catalytic Composition // European journal Organic Chemistry, 2014, Volume 2014, Issue 21. - pp. 4663-4670.
3. Qin Wang, Lina Pu. Diverse Transformations of Chiral Propargylic Alcohols Generated by BINOL-Catalyzed Alkyne Addition to Aldehydes // Synlett, 2013, Volume 24. - pp. 1340-1363.
4. Trofimov, B. A. Acetylene and its derivatives in reactions with nucleophiles: recent advances and current trends. Current Organic Chemistry, 2002. 6(13), pp. 1121-1162.
5. Cuibo Liu, Zhongxin Chen, Shibo Xi, Kian Ping Loh, Huan Yan, Ming Joo Koh The Nazarov cyclization // Synform, 2020. pp. 43-49.
6. Francis Mariaraj Irudayanathan, Jimin Kim, Kwang Ho Song, Prof. Sunwoo Lee Transition-Metal-Free Decarboxylative Coupling Reactions for the Synthesis of Propargyl Alcohols // Asian Journal of Organic Chemistry, 2016. Volume 5, Issue 9, pp. 1148-1154.
7. Yusupova Lola A., Nurmanov Suvon E. QUANTUM–CHEMICAL CALCULATIONS AND MATHEMATICAL MODELATION OF SYNTHESIS OF ACETYLENICAL DIOLS //Austrian Journal of Technical and Natural Sciences. – С. 66-74
8. Berguerand, C., Yuranov, I., Cárdenas-Lizana, F., Yuranova, T., & Kiwi-Minsker, L. (2014). Size-controlled pd nanoparticles in 2-butyne-1, 4-diol hydrogenation: Support effect and kinetics study. The Journal of Physical Chemistry C, 118(23), 12250-12259
9. Тургунов, Э., Холмуродова, Л. Э., & Джумагулов, Ш. Х. (2018). Каталитическое галогенирование ацетиленовых моно-и диаминов. Universum: химия и биология, (4 (46)), 16-23.
10. Содиков, М. К., Хужаназарова, С. Р. К., & Тургунов, Э. (2021). СИНТЕЗ ПРОСТЫХ И СЛОЖНЫХ ЭФИРОВ АЦЕТИЛЕНОВЫХ СПИРТОВ. Universum: химия и биология, (7-1 (85)), 85-90.
11. Turg‘unov, E., Nizamov, I., & Sodiqov, M. (2023). BUTIN-2-DIOL-1, 4 OLINISHI VA UNING XOSSALARI. Theoretical and experimental chemistry and modern problems of chemical technology, 1(01).
12. Nizamov, I., Toshpulatova, M., & Nizomov, Q. (2022). UNDERSTANDING THE NOBEL PRIZE. THE WINNERS OF THE NOBEL PRIZE IN CHEMISTRY. International Bulletin of Medical Sciences and Clinical Research, 2(12), 39-43.
